Tiêu chuẩn quốc tế

• Số hiệu / Standard Number: ASTM D7731-11E1
• Năm ban hành / Publication date: 2011
• Tình trạng / Status: W - Hết hiệu lực
• Tên tiếng Anh / Title in English: Standard Test Method for Determination of Dipropylene Glycol Monobutyl Ether and Ethylene Glycol Monobutyl Ether in Sea Water by Liquid Chromatography/Tandem Mass Spectrometry (LC/MS/MS)
• Chỉ số phân loại Quốc tế (ICS) / By field: 13.060.50 - Nghiên cứu chất hoá học trong nước
• Số trang / Page: 10

Phạm vi áp dụng / Scope of standard

1.1 This procedure covers the determination of Dipropylene Glycol Monobutyl Ether (DPGBE) and Ethylene Glycol Monobutyl Ether (EGBE) in sea water by direct injection using liquid chromatography (LC) and detection with tandem mass spectrometry (MS/MS). This analyte is qualitatively and quantitatively determined by this method. This method adheres to selected reaction monitoring (SRM) mass spectrometry.

1.2 The Detection Verification Level (DVL) and Reporting Range for DPGBE and EGBE are listed in Table 1.

1.2.1 The DVL is required to be at a concentration at least 3 times below the Reporting Limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 and Fig. 2 display the signal/noise ratio of the single reaction monitoring (SRM) transition.

1.2.2 The reporting limit is the concentration of the Level 1 calibration standard as shown in Table 4 for DPGBE and EGBE, taking into account the 20% sample preparation dilution factor.